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Mechanism of CO32- substitution in carbonate-fluorapatite: Evidence from FTIR spectroscopy, 13C NMR, and quantum mechanical calculations---Reply to Nathan
Mechanism CO32- substitution carbonate-fluorapatite Evidence FTIR spectroscopy 13C NMR quantum mechanical calculations---Reply Nathan
2012/4/5
In the critical comment byNathan (1996), the author essentially claims that the samples used in our study (Regnier et al. 1994) werenot very appropriate to dem-onstrate the absence of C03P-. Furthermo...
Mechanism of CO32- substitution in carbonate-fluorapatite: Evidence from FTIR spectroscopy, 13C NMR, and quantum mechanical calculations---Discussion
Mechanism CO32- substitution carbonate-fluorapatite Evidence FTIR spectroscopy 13C NMR quantum mechanical calculations---Discussion
2012/4/5
The carbonate substitution in apatite continues to pro-voke controversies. In a recent paper, Regnier etal. (1994) challenged the existence of the hypothetical C03P- ion in carbonate-fluorapatite (fra...