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Poly(vinyl chloride)-supported Pd(Ⅱ) complex as an efficient catalyst for Heck and Cu-free Sonogashira reactions under aerobic conditions
Heck reaction Sonogashira reaction Aryl halide Poly(vinyl chloride)-anchored palladium(Ⅱ) dithizone complex
2014/3/8
A novel poly(vinyl chloride)-supported Pd complex was found to be a highly active catalyst for the Heck and Sonogashira reactions of aryl halides under aerobic conditions. The complex is thermally sta...
Synthesis, structural analysis and evaluation of the catalytic activity of a non-symmetric N-(salicylidene)diethylenetriamine complex of copper(II)（图）
Crystal structure Copper(II) complex Non-symmetric Schiff base Catalyst Hydrogen peroxide
2013/9/26
A new copper(II) complex of a non-symmetric Schiff base, [CuII(saldien)(H2O)]+ (1), has been synthesized and characterized by elemental analysis and several other spectroscopic methods (Hsaldien = N-(...
Catalytic Activity of Dual Metal Cyanide Complex in Multi-component Coupling Reactions（图）
dual metal cyanide multi-component coupling reaction acid catalyst
2013/10/11
Several dual metal cyanide catalysts were prepared from potassium ferrocyanide, metal chloride (where metal = Zn2+, Mn2+, Ni2+, Co2+ and Fe2+), t-butanol (complexing agent) and PEG-4000 (co-complexing...