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A Ni metal form was used to carry the Ru catalyst to induce the hydrogen gas from the NaBH4 solution. Results show the Ni material was replaced by Ru material. Ru has been coating twice or more to cov...
Notes on ephesite,terskite,Na-komarovite,ceriopyrochlore-(Ce),joaquinite-(Ce) and other minerals from the Ilimaussaq alkaline complex,South Greenland.
Abstract: Clinoptilolite and mordenite occur as diagenetic products of medium-grained, moderately welded and poorly sorted pyroclastic flows belonging to the Tertiary calc-alkaline volcanism of Sardin...
The shear viscosities of melts in the system Na-Fe-Si-O-F-Cl were determined over a wide range of temperatures (400–1200 8 C) at 1 atm pressure in air. The compositions are based on the addition of Fe...
Abstract: Ferruginous beidellites with Al:Fe atomic ratios up to 2.36 were obtained when solutions containing Al, Fe2+ and H4SiO4 were adjusted to pH 8.5 with Ca(OH)2 and incubated at 95 癈 in the pres...
Experiments on tonalite and granodiorite wereperformed at conditions ranging from 2.1 to 18kbar and 550 to 850°C to establish the magmatic stability field ofepidote as a function ofP, T,and f02. Atwat...
The crystallization kinetics of goethite were studied colorimetrically under highly alkaline conditions (pH 10.1–12.2) at temperatures from 40° to 85°C. Color changes during crystallization from fresh...
Electrophoretic mobility of imogolite has been reported as positive (migration toward the negative electrode) below pH 9, and zero above pH 9. However, when mobility of dilute imogolite suspensions (5...
Fe(II) and Fe(III) in various proportions were coprecipitated by NH3 at pH ≈ 11. The Fe(II)/Fe(III) ratio (x) was varied from 0.10 to 0.50. After stabilization by aging at pH ≃ 8 in anaerobic co...
Abstract: At pH 12 Co-ferrihydrite transformed to either Co-goethite or Co-magnetite, the latter compound appearing at Co additions of > 18 mole %. Although Co was readily taken up by the magnetite st...
Phillipsite is a common constituent in diagenetically altered rhyolitic vitric tufts of Cenozoic saline, alkaline-lake deposits where it occurs as spherulites or aggregates of prismatic crystals. This...
The transformation of hausmannite (Mn3O4) into a K-bearing, 7-A phyllomanganate (K-birnessite) in KOH was followed using X-ray powder diffraction and transmission electron microscopy. The transformati...
Abstract: The transformation of ferrihydrite to goethite and/or hematite in alkaline media is strongly retarded by the presence of silicate species. These species probably stabilize ferrihydrite by ad...
Abstract: In the presence of Mn(II), ferrihydrite transforms into Mn-goethite and/or jacobsite. Chemical analysis showed that as much as 15 mole % Mn replaced Fe in the goethite structure. If Mn(III) ...
Abstract: The instability of palygorskite and sepiolite under soil conditions was investigated to determine if these fibrous minerals transform directly to smectite under laboratory conditions. The tr...

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