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Synchrotron based Transmission x-ray microscopy reveals smectite fine structure in an aqueous environment
Synchrotron Transmission x-ray microscopy reveals smectite fine structure aqueous environment
2012/3/30
The unusual behaviour of smectites, the ability to change volume when wetted (swelling) or dried (shrinking), make soil containing smectites very unstable and hazardous for the building industry due t...
Water mobility in smectite
Water mobility smectite
2012/3/30
The hydrogen in smectite can be broadly separated into five major types according to the association with (i) structural hydroxyl groups, (ii) interlayer water bonded directly to the interlayer cation...
The development of the later stages of the Murray Basin and the development of the smectite (bentonite) clays
development later stages Murray Basin development smectite (bentonite) clays
2012/3/30
This talk will be in two sections – the first part will discuss the development of the Murray Basin from the start of the final marine incursion (Loxton/Parilla Sand) until the present and will discus...
Equilibrium desorption isotherms of water, ethanol, ethyl acetate, and toluene on a sodium smectite clay
Clay Dynamic vapour sorption Ethanol Ethyl acetate Knudsen thermogravimetry Smectite Sorption isotherm Toluene Water
2011/11/10
Abstract Desorption isotherms for water, ethanol, ethyl acetate and toluene from a sodium smectite clay have been determined by both dynamic vapor sorption (DVS) measurements and Knudsen thermogravim...
Comparison of Evolution of Trioctahedral Chlorite/Berthierine/Smectite in Coeval Metabasites and Metapelites from Diagenetic to Epizonal Grades
AEM Berthierine Bukk Mountains Chlorite Low-grade Metamorphism Reaction Progress Smectite TEM XRD
2011/12/5
Abstract: The evolution of texture, structure and chemical composition of chloritic clays in coeval pairs of metabasites and metapelites of a prograde sequence from the Bükk Mountains has been investi...
Transmission Electron Microscopy Study of Conversion of Smectite to Illite in Mudstones of the Nankai trough: Contrast with Coeval Bentonites
Bentonites Diagenesis Illite Marine Sediments Mixed-Layered I-S Nankai Trough Shales
2011/12/2
Abstract: Clay minerals in shales from cores at Site 808, Nankai Trough, have been studied using X-ray diffraction (XRD), scanning transmission electron microscopy (STEM), and analytical electron micr...
Three-Dimensional Crystal Structures of Illite-Smectite Minerals in Paleozoic K-Bentonites from the Appalachian Basin
Bentonite Cis-Vacant Octahedra Crystal Structure Illite-Smectite Polytype Rotational Disorder X-ray Diffraction
2011/12/2
Abstract: The three-dimensional crystal structures of illite-smectite (I-S) in K-bentonite samples from the Appalachian Basin are characterized by rotational disorder in the stacking sequence of 2:1 i...
Reaction Mechanisms of Smectite Illitization Associated with Hydrothermal Alteration from Ponza Island, Italy
Atomic Force Microscopy Chemical Analysis Illite Polytype Smectite XRD
2011/12/6
Abstract: A hydrothermally altered rhyolitic hyaloclastite from Ponza island, Italy, has four alteration zones with unique clay assemblages: (1) a non-pervasive argillic zone characterized by smectite...
Smectite Diagenesis in Neogene Marine Sandstone and Mudstone of the Niigata Basin, Japan
Authigenic Chlorite Diagenesis Illitization Mixed-Layer Illite-Smectite Pore Fluid Smectite Smectite-Illite Transformation
2011/12/2
Abstract: Illitization of smectite during progressive burial diagenesis occurs differently in sandstone and mudstone, which are interbedded in the sedimentary sequence of the Niigata basin. Reaction p...
Evolution of Fundamental-Particle Size during Illitization of Smectite and Implications for Reaction Mechanism
Crystal Growth Fundamental Particle Illite-Smectite Illitization Mechanism Lognormal Distribution Ostwald Ripening
2011/12/6
Abstract: Area-weighted thickness distributions of fundamental illite particles for samples of illite and illite-smectite from seven locations (including bentonites and hydrothermally altered pyroclas...
Stepwise Hydration of High-Quality Synthetic Smectite with Various Cations
Crystalline Swelling Hydration Interlayer Cation Smectite
2011/12/6
Abstract: Smectites synthesized from experiments at 5.5 GPa and 1500癈 are of high quality, crystals are large at >10 祄, and the 2:1 layers may have a homogeneous charge distribution. Smectite was exch...
Mg-Rich Smectite “Precursor” Phase in the Tagus Basin, Spain
Precursor Clay Smectite Stevensite Tagus Basin (Spain) Incipient Crystallization
2011/12/6
Abstract: The pink clays from the Tagus basin, Spain, were characterized by X-ray difraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM), and transmission electron microscopy...
Electron Microscopy Study of Volcanic Tuff Alteration to Illite-Smectite under Hydrothermal Conditions
Hydrothermal Alteration Illite-Smectite SEM-EDS TEM-AEM Volcanic Tuff
2011/12/6
Abstract: Experimental alteration of volcanic tuff from Almer韆, southeastern Spain, was performed in solutions with different Na/K ratios (0.01, 1, 10, and 100), different total salt concentrations (0...
Authigenesis of Trioctahedral Smectite in Magnesium-Rich Carbonate Speleothems in Carlsbad Cavern and Other Caves of the Guadalupe Mountains, New Mexico
Authigenesis Carlsbad Cavern Caves Dolomite Huntite Moonmilk Stevensite Trioctahedral Smectite
2011/12/6
Abstract: Trioctahedral smectite is a constituent of Mg-rich carbonate crusts and moonmilks (pasty deposits) in caves of the Guadalupe Mountains of southeastern New Mexico. Energy dispersive X-ray mic...
Effects of Iron Oxidation State and Organic Cations on Dioctahedral Smectite Hydration
Alkylammonium Ferric Iron Ferrous Iron HDTMA Hydrophilic Surface Hydrophobic Surface Interlayer Cation Oxidation Reduction Surface Hydration Swelling TMA TMPA
2011/12/6
Abstract: Reduction of structural Fe in Na-exchanged dioctahedral smectites decreases swellability in water, but because clay interlayers also collapse in the process the concomitant effect on surface...