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The thermal behavior and decomposition of kaolinite–potassium acetate intercalation complex was investigated through a combination of thermogravimetric analysis and infrared emission spectroscopy. Thr...
Kaolinite:NaCl intercalates with basal layer dimensions of 0.95 and 1.25 nm have been prepared by direct reaction of saturated aqueous NaCl solution with well-crystallized source clay KGa-1. The inter...
Abstract: 1-4-diazabicyclo[2,2,2]octane dihydrochloride (DABCO·2HCl) was reacted with two vermiculite samples to produce intercalates which, at room temperature, had relatively sharp, single crystal X...
If anilinium ions are intercalated into Llano vermiculite, the stacking order of adjacent silicate layers is increased, resulting in a relatively sharp single crystal X-ray diffraction (XRD) pattern. ...
57Fe Mössbauer spectra obtained at room temperature and 78 K for natural Mg-saturated, Ca-saturated, and benzidinium-intercalated vermiculite having a high tetrahedral iron content are presented....
The crystal structure of the kaolinite: dimethylsulfoxide (DMSO) intercalate (P1, a = 5.187(2), b = 8.964(3), c = 11.838(4) 侌, 兛 = 91.53(1)亱, 兝 = 108.59(2), 兞 = 89.92(1)亱) has been determined using sp...
A vermiculite-aniline intercalate with a basal spacing of 14.78 侌 was investigated by one- and two-dimensional X-ray diffraction methods. The intercalate, prepared by ion exchange between Na-saturated...
The thermal decomposition of a kaolinite:dimethyl sulfoxide intercalate has been studied by thermogravimetry. The decomposition is complete by 175°C and has a ΔH of 58 ± 5 kJ/mole of dimethyl sulfoxid...
The rates of dehydroxylation of smectites intercalated with the decomposition products of Ni(phen)3SO4 are from 2 to 4 times greater than those of clays without the heat-stable intercalate. These resu...
The diffusion of water in the title intercalate has been measured by quasielastic neutron scattering. The diffusion coefficient (6.1 × 10−7 cm2 s−1 at 23.5°C) is one order less than that f...
The thermal decomposition of the kaolinite: N-methylformamide intercalate [Al2Si2O5(OH)4·HCONHCH3] has been studied by differential scanning calorimetry (DSC). The decomposition starts at 355 K, finis...

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