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A desktop experiment has been done to show the nonlinearity in the I-V characteristics of an ion conducting electrochemical micro-system. Its chaotic dynamics is being reported for the first time whic...
A combined hydrological and chemical investigation was undertaken in a small moorland catchment at Plynlimon to determine the processes controlling storm runoff chemistry. Flow from natural soil pipe...
Abstract: This paper examines the ion-exchange properties of synthetic zeolite Na-Pc, which was produced from perlite-waste fines and has a SiO2:Al2O3 ratio of 4.45:1 and a cation-exchange capacity (C...
The charge of the expandable interlayers in a series of fourteen diagenetic illite/smectites (I/S) from lower Paleozoic K-bentonites was determined by the alkylammonium ion exchange method. The magnit...
Three montmorillonite samples, from Wyoming (particle size <0.2 &micro;m, 4.6 wt. % Fe2O3), Greece (<14 &micro;m, 6.5 wt. % Fe2O3), and Poland (0.5 wt. % Fe2O3, two fractions <2 &micro;m and 2–10 &mic...
Synthetic sodium birnessite, having a cation-exchange capacity (CEC) of 240 meq/100 g (cmol/kg) was transformed into Li, K, Mg, Ca, Sr, Ni, and Mn2+ cationic forms by ion exchange in an aqueous medium...
Montmorillonite-based catalysts were compared with an acidic ion-exchange resin of the type used industrially for the production of methyl t-butyl ether (MTBE) from methanol and isobutene or t-butanol...
The rate of dissolution of phlogopite in an open system was measured at low temperature and pressure and at pH 3–5. The maximum dissolution rate was achieved by maintaining extremely low ionic concent...
The pH, Eh, electrical conductivity (EC), and the amounts and valency of replaceable iron were measured periodically on Fe2+- and Fe3+-saturated montmorillonite and cation-exchange resin at three temp...
Abstract: The adsorption mechanism of iso-propylammonium (PAH+), the cationic component of Roundup, by various homoionic montmorillonites and the structures of the associations obtained in the interla...
Natural erionite was exhaustively ion exchanged with Na+ to give the anhydrous unit-cell composition (K1.9Na5.4Ca0.1Mg0.1)[(AlO2)7.4(SiO2)28.6]. A thermodynamic study of alkali and alkaline earth meta...
The binding of tris-bipyridyl metal complexes of the type M(bp)32+ (M = Fe2+, Cu2+, Ru2+) to hectorite surfaces is shown to occur by two mechanisms: (1) replacement of Na+ ions in the native mineral b...
On NH4- as well as on (C2H5)3NH-montmorillonite EDA was adsorbed in protonated form. The extent of protonation depended on the relative basicities and concentrations of the interacting compounds. In t...
Ethylenediamine (EDA) adsorbed from aqueous solution or vapor phase on Al-, Ca- and Mg-montmorillonite was retained to a more or less large extent in protonated form. The NH3+ :NH2 ratio decreased wit...
Abstract: Ethylenediamine (EDA) is adsorbed from aqueous solution on Na-, K- and Li-montmorillonite as the monoprotonated cation (EDAH+) through an ion-exchange process. On washing with distilled wate...

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